By Pedro J. Pérez (Ed.),Pedro J. Pérez
Over the previous decade, a lot examine attempt has been dedicated to the layout and synthesis of latest reagents and catalysts which may effect carbon-hydrogen bond activation, normally end result of the prospect that C−H activation may possibly let the conversion of inexpensive and ample alkanes into invaluable functionalized natural compounds.
Alkane C-H Activation through Single-Site steel Catalysis offers the present cutting-edge improvement within the catalytic structures for the catalytic trans-formations of alkanes lower than homogeneous stipulations. bankruptcy 1 deals a entire precis of the most discoveries learned up to now. bankruptcy 2 experiences the so-called electrophilic activation, initiated via Shulpín within the overdue 60s, and the bottom for the Catalytica system. bankruptcy three examines the catalytic borylation of alkanes, stumbled on through Hartwig, while bankruptcy four offers an up to date imaginative and prescient of the alkane dehydrogenation response. bankruptcy five covers the oxygenation of C-H bonds, a box of huge curiosity with bioinorganic im-plications, and eventually bankruptcy 6 offers the functionalization of alkane C-H bonds by way of carbene or nitrene insertion.
The background of C-H bond activation, and the present learn defined during this e-book, spotlight the present learn and current the reader with an outlook of this box which is still explored via an more and more visionary and enthusiastic crew of natural, organometallic, organic and actual chemists.
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Alkane C-H Activation by Single-Site Metal Catalysis: 38 (Catalysis by Metal Complexes) by Pedro J. Pérez (Ed.),Pedro J. Pérez